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Mechanistic manifold in a hemoprotein-catalyzed cyclopropanation reaction with diazoketone

Donggeon Nam, John-Paul Bacik, Rahul L. Khade, Maria Camila Aguilera, Yang Wei, Juan D. Villada, Michael L. Neidig, Yong Zhang, Nozomi Ando & Rudi Fasan

Nature Communications, 2023, 14, 7985

DOI: 10.1038/s41467-023-43559-7

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Palladium and Iron Cocatalyzed Aerobic Alkene Aminoboration

Gay, B. L., Wang, Y., Bhatt, S., Tarasewicz, A., Cooke, D. J., Milem, E. G., Zhang, B., Gary, J. B., Neidig, M. L., & Hull, K. L.

J. Am. Chem. Soc. 2023, 145, 18939-18947.

DOI: 10.1021/jacs.3c05790

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Mechanistic Studies of Iron-PyBOX-Catalyzed Olefin Amino-Oxygenation with Functionalized Hydroxylamines

Radović, A.; Wolford, N. J.; Li, W.; Brennessel, W. W.; Xu, H.; Neidig, M. L.

Organometallics. 2023, 42, 1810-1817.

DOI: 10.1021/acs.organomet.3c00067

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Insight into Radical Initiation, Solvent Effects, and Biphenyl Production in Iron-Bisphosphine Cross-Couplings

Aguilera, M. C.; Gogoi, A. R.; Lee, W.; Liu, L.; Brennessel, W. W.; Gutierrez, O.; Neidig, M. L.

ACS Catal. 2023, 13, 8987-8996.

DOI: 10.1021/acscatal.3c02008

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Thermally Stable Redox Noninnocent Bathocuproine-Iron Complex for Cycloaddition Reactions

Féo, M.; Bakas, N. J.; Radović, A.; Parisot, W.; Clisson, A.; Chamoreau, L.; Mansour, Ratovelomanana-Vidal, V.,;Neidig, M. L.; Lefèvre, G. 

ACS Catal. 2023, 13, 4882-4893.

DOI: 10.1021/acscatal.3c00353

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The molecular-level effect of alkoxide additives in iron-catalyzed Kumada cross-coupling with simple ferric salts

Bakas, N. J.; Chourreu P.; Gayon, E.; Lefèvre, G.; Neidig, M. L.

Chem. Commun. 2023, 59, 1317-1320 

DOI: 10.1039/D2CC06257G