graphical abstract

Intermediates and mechanism in iron-catalyzed C-H methylation with trimethylaluminum

Bathia, S.; DeMuth, J.C.; Neidig M. L.

Chem. Commun. 2021, 57, 12784-12787 

 DOI: 10.1039/D1CC05607G

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Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes

Gaiser, A. N.; Celis-Barros, C.; White, F. D.; Beltrán-Leiva, M. J.; Sperling, J.; Salpage, S. R.; Poe, T. N.; Martinez, D. G.; Jian, T., Wolford, N. J.; Neidig, M. L., & Albrecht‐Schönzart, T. E.; et al.

Nat Commun. 2021, 12, 7230

DOI: 10.1038/s41467-021-27576-y

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Air-Stable Iron-Based Precatalysts for Suzuki-Miyaura Cross-Coupling Reactions between Alkyl Halides and Aryl Boronic Esters

Wong, A. K. K.; Zhang, B.; Li, B.; Neidig, M. L.; & Byers, J. A.

Org. Process Res. Dev. 2021, 25, 2461-2472

DOI: 10.1021/acs.oprd.1c00235

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General method for iron-catalyzed multicomponent radical cascades-cross-couplings

Liu, L.; Aguilera, M. C.; Lee, W.; Youshaw, C. R.; Neidig, M. L.; Gutierrez, O.

Science 2021, 374, 432-439

DOI: 10.1126/science.abj6005

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NHC Effects on Reduction Dynamics in Iron-Catalyzed Organic Transformations

Wolford, N. J.; Muñoz, S. B.; Neate, P. G. N.; Brennessel, W. W.; Neidig, M. L.

Chem. Eur. J. 2021, 27, 13651-13658

DOI: 10.1002/chem.202102070

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Cluster Supported by Redox-Active o-Phenylenediamide Ligands and Its Application toward Dinitrogen Reduction

Liang, Q.; DeMuth, J.; Radović, A.; Wolford, N. J.; Neidig, M. L.; & Song, D.

Inorg. Chem. 2021, 60, 13811-13820

DOI: 10.1021/acs.inorgchem.1c00683

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An anionic iron-hydride superstar for the isomerization of terminal alkenes

Aguilera, M.C.; Neidig, M.L.

Chem Catal. 2021, 1, 488-489

DOI: 10.1016/j.checat.2021.07.009

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Dilithium Amides as a Modular Bis-Anionic Ligand Platform for Iron-Catalyzed Cross-Coupling

Neate, P. G. N.; Zhang, B.; Conforti, J.; Brennessel, W. W.; Neidig, M. L.

Org. Lett. 2021, 23, 5958-5963

DOI: 10.1021/acs.orglett.1c02053

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Metal-carbon bonds of iron and manganese

Neidig, M.L., Bakas, N.J., Neate, P.G.N., Sears, J.D.

Comprehensive Coordination Chemistry III. 2021, 82-122

DOI: 10.1016/B978-0-08-102688-5.00050-7

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C-H activation/functionalization with earth abundant 3d transition metals

Neidig, M.L., DeMuth, J.C., Zhang, B.

Comprehensive Coordination Chemistry III. 2021, 260-310

DOI: 10.1016/B978-0-08-102688-5.00009-X

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Experimental and computational studies of the mechanism of iron-catalysed C-H activation/functionalisation with allyl electrophiles

DeMuth, J. C.; Song, Z.; Carpenter, S. H.; Boddie, T. E.; Radović, A.; Baker, T. M.; Gutierrez, O.; Neidig, M. L.

Chem. Sci. 2021, 12, 9398-9407

DOI: 10.1039/D1SC01661J

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Near-infrared C-term MCD spectroscopy of octahedral uranium(v) complexes

Curran, D. J.; Ganguly, G.; Heit, Y. N.; Wolford, N. J.; Minasian, S. G.; Löble, M. W.; Cary, S. K.; Kozimor, S. A.; Autschbach, J.; Neidig, M. L.

Dalton Trans. 2021, 50, 5483-5492

DOI: 10.1039/D1DT00513H

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Forged in iron

Neate, P. G. N.; Neidig, M. L.

Nat Rev Chem. 2021, 5, 223-224

DOI: 10.1038/s41570-021-00259-4

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Activation of ammonia and hydrazine by electron rich Fe(II) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe(III) amido intermediate

Nurdin, L.; Yang, Y.; Neate, P. G. N.; Piers, W. E.; Maron, L.; Neidig, M. L.; Lin, J.; Gelfand, B. S.

Chem. Sci. 2021,12, 2231-2241 

DOI: 10.1039/D0SC06466A

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C-Term Magnetic Circular Dichroism (MCD) Spectroscopy in Paramagnetic Transition Metal and f-Element Organometallic Chemistry

Wolford, N. J.; Radovic, A.; Neidig, M. L.

Dalton Trans. 2021, 50, 416-428

DOI: 10.1039/D0DT03730C

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Additive and Counterion Effects in Iron-Catalyzed Reactions Relevant to C-C Bond Formation

Bakas, N. J.; Neidig, M. L.

ACS Catal. 2021, 11, 8493-8503

DOI: 10.1021/acscatal.1c00928

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CHAPTER 7: Open Shell Iron Catalysis: Mechanistic Challenges, Approaches and Pitfalls

Neate, P.G.N.; Neidig, M.L.

RSC Catalysis Series. 2021, 231-245

DOI: 10.1039/9781788012775-00231